20161115 化學(選上講P149)
已知H3PO4的三個解離步驟之解離常數為Ka1=7.1×10-3,Ka2=6.2×10-8,Ka3=4.4×10-13,則下列0.1 M H3PO4溶液中各物種濃度的關係式中,何者正確?
(A)[H3PO4]+[H2PO4-]+[HPO42-]+[PO43-]=0.1 M
(B)[H2PO4-]+2 [HPO42-]+3 [PO43-]+[OH-]=[H+]
(C)[H2PO4-]≒[H+]=4.2×10-3M
(D)[HPO42-]=6.2×10-8M
(E)[PO43-]=1.2×10-18M(Ans:ABDE)
請詳細解說,感恩!:)